we have these records : 
using :
1
2
3
SELECT *
FROM user_working_hours
WHERE EXTRACT(HOUR_SECOND from date_start) between 100000 and 100500

using :
1
2
3
SELECT *
FROM user_working_hours
WHERE EXTRACT(HOUR_SECOND from date_start) between 100000 and 100600

using :
1
2
3
SELECT *
FROM user_working_hours
WHERE (EXTRACT(HOUR_SECOND from date_start) between 100000 and 100600) AND (EXTRACT(HOUR_SECOND from date_end) between 153000 and 153100)

just for the history, using :
1
2
3
SELECT *
FROM user_working_hours
WHERE HOUR(date_start)>15

origin - http://www.pipiscrew.com/?p=1658 mysql-query-datetime-field-only-by-time